Molybdenum(VI) complexes with N-substituted hydroxylamines

New molybdenum(VI) complexes with N-monoalkylsubstituted hydroxylamines have been synthesized and studied. The structure of [MoO 2 (C 2 H 5 NHO) 2 ] and [MoO 2 ( i -C 3 H 7 NHO) 2 ], whose distinguishing feature is the bidentate chelate coordination of the ligand to molybdenum with the formation of...

Full description

Saved in:
Bibliographic Details
Published in:Russian journal of inorganic chemistry 2013-12, Vol.58 (12), p.1446-1451
Main Authors: Beirakhov, A. G., Orlova, I. M., Il’in, E. G., Sakharov, S. G., Goeva, L. V., Churakov, A. V., Surazhskaya, M. D., Mikhailov, Yu. N.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Coordination Compounds
Inorganic Chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:New molybdenum(VI) complexes with N-monoalkylsubstituted hydroxylamines have been synthesized and studied. The structure of [MoO 2 (C 2 H 5 NHO) 2 ] and [MoO 2 ( i -C 3 H 7 NHO) 2 ], whose distinguishing feature is the bidentate chelate coordination of the ligand to molybdenum with the formation of the three-membered NMoO chelate ring, has been determined by X-ray diffraction.
ISSN:0036-0236
1531-8613
DOI:10.1134/S003602361312005X