Complexes of some tervalent metals with N-alkyl(benzyl)nitrozohydroxylamine derivatives

Twenty two new complexes of some tervalent metals (aluminum, chromium, iron, and lanthanides) with nitrozohydroxylamine N -alkyl(benzyl) derivatives ML 3 m · n H 2 O, ( m = 1‒5) were synthesized and isolated in a crystalline state. The crystal and molecular structures of the iron(III) complex with N...

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Bibliographic Details
Published in:Russian journal of inorganic chemistry 2016-06, Vol.61 (6), p.718-725
Main Authors: Kovalchukova, O. V., Namichemazi, Nasrin, Bostanabad, A. Sh, Stash, A. I., Strashnova, S. B., Zuzin, I. N.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Coordination Compounds
Inorganic Chemistry
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Summary:Twenty two new complexes of some tervalent metals (aluminum, chromium, iron, and lanthanides) with nitrozohydroxylamine N -alkyl(benzyl) derivatives ML 3 m · n H 2 O, ( m = 1‒5) were synthesized and isolated in a crystalline state. The crystal and molecular structures of the iron(III) complex with N -(2-fluorobenzyl)- N -nitrozohydroxylamine were determined by X-ray diffraction. An octahedral coordination of the central ion and a bidentate chelating coordination of the organic ligand were established. The spectral criteria of coordination of nitrozohydroxylamine alkyl(benzyl) derivatives were determined, and the complexation processes in solutions were studied.
ISSN:0036-0236
1531-8613
DOI:10.1134/S0036023616060140