Kinetic model of coherent synchronized ethylene monooxidation by hydrogen peroxide on a biomimetic catalyst, per-FTPhPFe3+OH/Al2O3

A kinetic model that fits the experimental data is studied on the basis of the most probable mechanism of ethylene oxidation by hydrogen peroxide over a biomimetic catalyst, perfluorinated iron (III) tetraphenylporphyrin, deposited on aluminum oxide (per-FTPhPFe 3+ OH/Al 2 O 3 ). Effective rate cons...

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Bibliographic Details
Published in:Russian Journal of Physical Chemistry A 2011-12, Vol.85 (12), p.2115-2120
Main Authors: Nasirova, U. V., Nagieva, I. T., Gasanova, L. M., Nagiev, T. M.
Format: Article
Language:English
Subjects:
Chemical Kynetics and Catalysis
Chemistry
Chemistry and Materials Science
Physical Chemistry
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Summary:A kinetic model that fits the experimental data is studied on the basis of the most probable mechanism of ethylene oxidation by hydrogen peroxide over a biomimetic catalyst, perfluorinated iron (III) tetraphenylporphyrin, deposited on aluminum oxide (per-FTPhPFe 3+ OH/Al 2 O 3 ). Effective rate constants for the catalase and oxygenase reactions and their effective activation energies are found.
ISSN:0036-0244
1531-863X
DOI:10.1134/S0036024411120235