Nanoporous functional organosilicas for sorption of toxic ions

The chemical immobilization of β-cyclodextrin and its bromoacetyl and thiosemicarbazidoacetyl functional derivatives on the surface of highly disperse amorphous nanoporous silica was performed. β-Cyclodextrin-containing silicas were found to have high affinity to mercury(II), cadmium(II), and zinc(I...

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Published in:Russian Journal of Physical Chemistry A 2014-03, Vol.88 (3), p.489-493
Main Authors: Belyakova, L. A., Lyashenko, D. Yu
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Language:English
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Chemistry
Chemistry and Materials Science
Physical Chemistry
Physical Chemistry of Nanoclusters and Nanomaterials
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description The chemical immobilization of β-cyclodextrin and its bromoacetyl and thiosemicarbazidoacetyl functional derivatives on the surface of highly disperse amorphous nanoporous silica was performed. β-Cyclodextrin-containing silicas were found to have high affinity to mercury(II), cadmium(II), and zinc(II) cations. Supramolecular surface structures formed whose chemical composition depends on the nature of the sorbed cations and the functional substituents in the attached β-cyclodextrin molecules.
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subjects Chemistry
Chemistry and Materials Science
Physical Chemistry
Physical Chemistry of Nanoclusters and Nanomaterials
title Nanoporous functional organosilicas for sorption of toxic ions
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