Interaction between Mo132 nanocluster polyoxometalate and solvents

The interaction between solid Mo 132 nanocluster polyoxometalate with the structure of a keplerate and solvents of different natures (e.g., water, alcohols, hexane, and tetrachloromethane) is studied thermochemically. NMR spectroscopy is used to analyze interactions in solid polyoxometalate-organic...

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Bibliographic Details
Published in:Russian Journal of Physical Chemistry A 2014-12, Vol.88 (12), p.2179-2182
Main Authors: Ostroushko, A. A., Safronov, A. P., Tonkushina, M. O., Korotaev, V. Yu, Barkov, A. Yu
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Physical Chemistry
Physical Chemistry of Nanoclusters and Nanomaterials
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Summary:The interaction between solid Mo 132 nanocluster polyoxometalate with the structure of a keplerate and solvents of different natures (e.g., water, alcohols, hexane, and tetrachloromethane) is studied thermochemically. NMR spectroscopy is used to analyze interactions in solid polyoxometalate-organic compound systems in a gaseous medium. Data are collected on sorption interactions between a Mo 132 nanocluster and camphor.
ISSN:0036-0244
1531-863X
DOI:10.1134/S0036024414120231