Contraction of aqueous solutions of monoatomic alcohols

The temperature dependences of the contraction of water solutions of monoatomic alcohols are studied. The analysis is performed using theoretical concepts developed earlier on the basis of a virial expansion of the equation of state for solutions. The contraction and the character of its temperature...

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Bibliographic Details
Published in:Russian Journal of Physical Chemistry A 2015-01, Vol.89 (1), p.51-56
Main Authors: Gotsul’skii, V. Ya, Malomuzh, N. P., Timofeev, M. V., Chechko, V. E.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Physical Chemistry
Physical Chemistry of Solutions
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Summary:The temperature dependences of the contraction of water solutions of monoatomic alcohols are studied. The analysis is performed using theoretical concepts developed earlier on the basis of a virial expansion of the equation of state for solutions. The contraction and the character of its temperature dependence can differ substantially in both value and sign, depending on the combinations molecular parameters. The available experimental data are compared.
ISSN:0036-0244
1531-863X
DOI:10.1134/S0036024415010070