High-sensitivity titration microcalorimeter

A differential titration microcalorimeter for studying intermolecular interactions in solutions has been designed. To increase the speed of the instrument, the dynamic correction method has been used. It has been shown that electrical calibration of the microcalorimeter is consistent with its chemic...

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Bibliographic Details
Published in:Russian Journal of Physical Chemistry A 2015-02, Vol.89 (2), p.346-349
Main Authors: Velikov, A. A., Grigoryev, S. V., Chuikin, A. V.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Methods and Techniques of Physicochemical Studies
Physical Chemistry
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Summary:A differential titration microcalorimeter for studying intermolecular interactions in solutions has been designed. To increase the speed of the instrument, the dynamic correction method has been used. It has been shown that electrical calibration of the microcalorimeter is consistent with its chemical calibration. The use of the instrument for measuring the integral heats of dilution of 1-propanol has been demonstrated.
ISSN:0036-0244
1531-863X
DOI:10.1134/S0036024415020351