Thermodynamic characteristics of scandium trichloride and tribromide in the condensed state

Literature data are analyzed and possibility of calculating thermodynamic functions for ScCl 3 and ScBr 3 (experimental data for which are very few) is explored. Equations for approximating the temperature dependence for the heat capacity of ScCl 3 and ScBr 3 are obtained for the temperature range o...

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Published in:Russian Journal of Physical Chemistry A 2015-07, Vol.89 (7), p.1127-1130
Main Authors: Aristova, N. M., Belov, G. V.
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Language:English
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Chemical Thermodynamics and Thermochemistry
Chemistry
Chemistry and Materials Science
Physical Chemistry
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description Literature data are analyzed and possibility of calculating thermodynamic functions for ScCl 3 and ScBr 3 (experimental data for which are very few) is explored. Equations for approximating the temperature dependence for the heat capacity of ScCl 3 and ScBr 3 are obtained for the temperature range of 298.15 K to melting point. Using the available data for liquid phase properties, tables of the thermodynamic functions of ScCl 3 and ScBr 3 (heat capacity, reduced Gibbs energy, and change in enthalpy) are calculated up to 2000 K. The obtained data are entered into the database of the IVTANTERMO software package.
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Chemistry and Materials Science
Physical Chemistry
title Thermodynamic characteristics of scandium trichloride and tribromide in the condensed state
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