Kinetics and Mechanism of the Formation of the Solid Phase during the Deposition of PbSe Films Using Inhibitors of Selenocarbamide Oxidation

Data on the kinetics and mechanism of the formation of a solid phase during the hydrochemical deposition of lead selenide films with inhibitors of selenocarbamide oxidation (sodium sulfite, ascorbic acid, and tin chloride) are systematized and analyzed. The effective rate constants of the conversion...

Full description

Saved in:
Bibliographic Details
Published in:Russian Journal of Physical Chemistry A 2020-12, Vol.94 (12), p.2435-2440
Main Authors: Yurk, V. M., Maskaeva, L. N., Markov, V. F., Bel’tseva, A. V., Uritskaya, A. A.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
ON THE 100th ANNIVERSARY OF URAL FEDERAL UNIVERSITY
Physical Chemistry
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Data on the kinetics and mechanism of the formation of a solid phase during the hydrochemical deposition of lead selenide films with inhibitors of selenocarbamide oxidation (sodium sulfite, ascorbic acid, and tin chloride) are systematized and analyzed. The effective rate constants of the conversion of a lead salt to selenide and the thickness of PbSe films are shown to depend on the nature and concentrations of the inhibiting additives. The effect of the nature of the inhibitors on the mechanism of nucleation is studied via dynamic light scattering. The stronger inhibiting effect of the simultaneous presence of sodium sulfite and ascorbic acid in the reaction mixture had on the process of selenocarbamide oxidation is confirmed.
ISSN:0036-0244
1531-863X
DOI:10.1134/S0036024420120341