Thio derivatives of cyclopentanone and cyclohexanone

Mono-and bis(methylthiomethyl) substituted derivatives of cyclopentanone and cyclohexanone were obtained on the basis of natural methylmercaptan via the alkylthiomethylation of ketones, and these derivatives were converted into the corresponding γ-hydroxysulfides and ketosulfones via reduction with...

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Bibliographic Details
Published in:Petroleum chemistry 2008-09, Vol.48 (5), p.393-397
Main Authors: Baeva, L. A., Ulendeeva, A. D., Arslanova, D. D., Shitikova, O. V., Galkin, E. G., Lyapina, N. K.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Industrial Chemistry/Chemical Engineering
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Summary:Mono-and bis(methylthiomethyl) substituted derivatives of cyclopentanone and cyclohexanone were obtained on the basis of natural methylmercaptan via the alkylthiomethylation of ketones, and these derivatives were converted into the corresponding γ-hydroxysulfides and ketosulfones via reduction with sodium borohydride and oxidation with hydrogen peroxide, respectively.
ISSN:0965-5441
1555-6239
DOI:10.1134/S0965544108050101