Structural features of compounds of the sillenite family

It is shown that the real composition and structure of phases belonging to the sillenite family can be determined using a complex of techniques (diffraction methods, vibrational and X-ray absorption spectroscopy, and electron probe X-ray microanalysis) with a subsequent crystal-chemical analysis of...

Full description

Saved in:
Bibliographic Details
Published in:Crystallography reports 2014-05, Vol.59 (3), p.353-361
Main Authors: Mel’nikova, T. I., Kuz’micheva, G. M., Bolotina, N. B., Rybakov, V. B., Zubavichus, Ya. V., Sadovskaya, N. V., Mar’ina, E. A.
Format: Article
Language:English
Subjects:
Crystallography and Scattering Methods
Physics
Physics and Astronomy
Structure of Inorganic Compounds
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:It is shown that the real composition and structure of phases belonging to the sillenite family can be determined using a complex of techniques (diffraction methods, vibrational and X-ray absorption spectroscopy, and electron probe X-ray microanalysis) with a subsequent crystal-chemical analysis of the data. Refined compositions are presented for phases of nominal composition Bi 24 M 2 O 40 with M = Zn 2+ , Al 3+ , Ga 3+ , Fe 3+ , Si 4+ , Ti 4+ , Mn 4+ , and P 5+ , which demonstrate types and concentrations of point defects as functions of the M type.
ISSN:1063-7745
1562-689X
DOI:10.1134/S1063774514030134