Synthesis, Characterization, and Crystal Structure of (E)-4-(2-(4-Cyanobenzylidene)hydrazinyl)benzonitrile Dimethyl Sulfoxide Hemisolvate

( E )-4-(2-(4-Cyanobenzylidene)hydrazinyl)benzonitrile dimethyl sulfoxide hemisolvate, C 15 H 10 N 4 ⋅ 0.5C 2 H 6 OS is synthesized following a green protocol and its crystal structure is determined by X-ray structure analysis. The crystals are monoclinic, sp. gr. C 2/ c , Z = 4. Two benzonitrile mo...

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Bibliographic Details
Published in:Crystallography reports 2020-12, Vol.65 (7), p.1191-1194
Main Authors: Sharma, V., Karmakar, I., Brahmachari, G., Gupta, V. K.
Format: Article
Language:English
Subjects:
Crystallography and Scattering Methods
Physics
Physics and Astronomy
Structure of Organic Compounds
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Summary:( E )-4-(2-(4-Cyanobenzylidene)hydrazinyl)benzonitrile dimethyl sulfoxide hemisolvate, C 15 H 10 N 4 ⋅ 0.5C 2 H 6 OS is synthesized following a green protocol and its crystal structure is determined by X-ray structure analysis. The crystals are monoclinic, sp. gr. C 2/ c , Z = 4. Two benzonitrile moieties forms a dihedral angle of 7.62° with each other. The crystal structure is stabilized by N–H⋅⋅⋅O hydrogen bond involving the DMSO solvate molecule.
ISSN:1063-7745
1562-689X
DOI:10.1134/S1063774520070160