Crystal structure and spectroscopic properties of ciprofloxacinium pentachloroantimonate(III) monohydrate (C17H19N3O3F)SbCl5 · H2O

Synthesis, X-ray diffraction, IR and luminescence spectroscopic studies of the monohydrate of pentachloroantimonate(III) of doubly protonated ciprofloxacin (C 17 H 19 N 3 O 3 F)SbCl 5 · H 2 O ( I ) were performed. The structure of I is formed by SbCl 6 octahedra combined into polymeric chains [SbCl...

Full description

Saved in:
Bibliographic Details
Published in:Russian journal of coordination chemistry 2008-09, Vol.34 (9), p.647-652
Main Authors: Gerasimenko, A. V., Polishchuk, A. V., Karaseva, E. T., Karasev, V. E.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Physical Chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Synthesis, X-ray diffraction, IR and luminescence spectroscopic studies of the monohydrate of pentachloroantimonate(III) of doubly protonated ciprofloxacin (C 17 H 19 N 3 O 3 F)SbCl 5 · H 2 O ( I ) were performed. The structure of I is formed by SbCl 6 octahedra combined into polymeric chains [SbCl 5 ] n 2 n − through common vertices, ciprofloxacinium cations (CfH 3 ) 2+ , and water molecules linked by hydrogen bonds. CfH is protonated at the carbonyl oxygen atom and the terminal nitrogen atom of the piperazinyl group. The electronic and geometric aspects determining the luminescence properties of I and of related compounds are discussed.
ISSN:1070-3284
1608-3318
DOI:10.1134/S1070328408090030