Nickel(I) complex as the final product of the sequence of spontaneous transformations in the system Ni(allyl)2-(2,6-diisopropylphenyl)diazabutadiene

A reaction of Ni(Allyl) 2 with bis(2,6-diisopropylphenyl)diazabutadiene gave an imino amide allyl nickel(II) complex ( I ). Complicated rearrangements of the imino amide ligand in the coordination sphere of complex I spontaneously yielded a paramagnetic Ni(I) π-allyl complex as a final reaction prod...

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Bibliographic Details
Published in:Russian journal of coordination chemistry 2012-06, Vol.38 (6), p.416-425
Main Authors: Kraikivskii, P. B., Saraev, V. V., Bocharova, V. V., Romanenko, G. V., Matveev, D. A., Petrovskii, S. K., Kuzakov, A. S.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Physical Chemistry
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Summary:A reaction of Ni(Allyl) 2 with bis(2,6-diisopropylphenyl)diazabutadiene gave an imino amide allyl nickel(II) complex ( I ). Complicated rearrangements of the imino amide ligand in the coordination sphere of complex I spontaneously yielded a paramagnetic Ni(I) π-allyl complex as a final reaction product. The nickel complexes produced in this system were studied by EPR, IR, and 2D NMR spectroscopy and mass spectrometry. Structure I was examined by X-ray diffraction.
ISSN:1070-3284
1608-3318
DOI:10.1134/S1070328412050053