New zirconium fluoride complexes (NH4)6MZr4F23 (M = K, Rb, and Cs): Synthesis and physicochemical properties

Ammonium-containing zirconium fluoride complexes of the formula (NH 4 ) 6 MZr 4 F 23 (M = K, Rb, and Cs) were obtained and studied. The complexes crystallize in the orthorhombic system. Their unit cell parameters were determined. The IR absorption spectra of the complexes in the 350–4000 cm −1 range...

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Bibliographic Details
Published in:Russian journal of coordination chemistry 2013-04, Vol.39 (4), p.312-315
Main Authors: Antokhina, T. F., Kaidalova, T. A., Savchenko, N. N., Ignat’eva, L. N.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Physical Chemistry
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Summary:Ammonium-containing zirconium fluoride complexes of the formula (NH 4 ) 6 MZr 4 F 23 (M = K, Rb, and Cs) were obtained and studied. The complexes crystallize in the orthorhombic system. Their unit cell parameters were determined. The IR absorption spectra of the complexes in the 350–4000 cm −1 range were recorded and examined.
ISSN:1070-3284
1608-3318
DOI:10.1134/S1070328413040015