Self assembly of three new copper coordination polymers based on N-[(3-pyridine)-sulfonyl]aspartate: Synthesis and structure

Three new copper coordination polymers [Cu(L) · 6H 2 O] n ( I ), [Cu 2 (L) 2 ] n ( II ), and [Cu(HL) 2 ] n ( III ), where H 2 L is N-[(3-pyridine)-sulfonyl]aspartate, have been synthesized and characterized by singlecrystal X-ray diffraction (CIF files CCDC nos. 1435871 ( I ), 1435872 ( II ), 143587...

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Bibliographic Details
Published in:Russian journal of coordination chemistry 2016-04, Vol.42 (4), p.285-291
Main Authors: Liao, B. L., Li, S. X., Guo, J. J., Jia, J. J., Jiang, Y. M.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Physical Chemistry
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Summary:Three new copper coordination polymers [Cu(L) · 6H 2 O] n ( I ), [Cu 2 (L) 2 ] n ( II ), and [Cu(HL) 2 ] n ( III ), where H 2 L is N-[(3-pyridine)-sulfonyl]aspartate, have been synthesized and characterized by singlecrystal X-ray diffraction (CIF files CCDC nos. 1435871 ( I ), 1435872 ( II ), 1435873 III ), elemental analysis and IR spectra. Moreover, the variable-temperature magnetic susceptibility had been studied for complex I . A structural comparison of these polymers suggests that different reaction temperatures play important role in the construction of resulting architectures for I – III .
ISSN:1070-3284
1608-3318
DOI:10.1134/S1070328416040035