Oxidation of magnesium with cyclopentadienyl(triphenylphosphine)nickel chloride in aprotic solvents

The products of magnesium oxidation with cyclopentadienyl(triphenylphosphine)nickel chloride were revealed. Effective equilibrium constants of adsorption of the reagents on the metal surface, entropy and enthalpy of these processes, rate constants, and activation energy were determined. A probable s...

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Bibliographic Details
Published in:Russian journal of general chemistry 2008-08, Vol.78 (8), p.1488-1491
Main Authors: Maslennikov, S. V., Panteleev, S. V., Spirina, I. V., Maslennikov, V. P.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
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Summary:The products of magnesium oxidation with cyclopentadienyl(triphenylphosphine)nickel chloride were revealed. Effective equilibrium constants of adsorption of the reagents on the metal surface, entropy and enthalpy of these processes, rate constants, and activation energy were determined. A probable scheme of the process is assumed.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363208080045