Synthesis and optical properties of (S)-Nobin

A preparative method of synthesis of optically pure S -2-amino-2′-hydroxy-1,1′-binaphthyl ( S -Nobin), the precoursor in the synthesis of other asymmetric 1,1-binaphthyls applied as the ligands at the creation of the catalysts of asymmetric synthesis, is modified. The UV and CD spectra of this compo...

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Bibliographic Details
Published in:Russian journal of general chemistry 2009-05, Vol.79 (5), p.962-966
Main Authors: Studentsov, E. P., Piskunova, O. V., Skvortsov, A. N., Skvortsov, N. K.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
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Summary:A preparative method of synthesis of optically pure S -2-amino-2′-hydroxy-1,1′-binaphthyl ( S -Nobin), the precoursor in the synthesis of other asymmetric 1,1-binaphthyls applied as the ligands at the creation of the catalysts of asymmetric synthesis, is modified. The UV and CD spectra of this compound were studied in detail and essential dependence of spectral information on the solvent nature was shown.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363209050168