Reactions of 1-bromo-1-nitro-3,3,3-trichloropropene with O- and N-nucleophiles

Reactions of 1-bromo-1-nitro-3,3,3-trichloropropene with alcohols, benzidine and o -, m -, and p -phenylenediamines was investigated and the reaction conditions were developed. The alkoxylation and amination products and an unusual nitrogen-containing bis-aziridine were obtained; their structures we...

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Bibliographic Details
Published in:Russian journal of general chemistry 2010-12, Vol.80 (12), p.2460-2465
Main Authors: Stukan’, E. V., Makarenko, S. V., Berkova, G. A., Berestovitskaya, V. M.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
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Summary:Reactions of 1-bromo-1-nitro-3,3,3-trichloropropene with alcohols, benzidine and o -, m -, and p -phenylenediamines was investigated and the reaction conditions were developed. The alkoxylation and amination products and an unusual nitrogen-containing bis-aziridine were obtained; their structures were characterized by the spectral (IR, 1 H, 13 C NMR, HMQC, and HMBC) methods.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363210120108