Synthesis and structure of triphenylantinony dimethacrylate

Triphenylantinony dimethacrylate Ph 3 Sb(O 2 CMe=CH 2 ) 2 was obtained in the reaction of triphenylantimony with methacrylic acid in the presence of hydrogen peroxide. The structure of the product was confirmed by elemental analysis, IR and 1 H NMR spectroscopy. According to X-ray diffraction analys...

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Bibliographic Details
Published in:Russian journal of general chemistry 2011-03, Vol.81 (3), p.493-496
Main Authors: Gushchin, A. V., Shashkin, D. V., Prytkova, L. K., Somov, N. V., Baranov, E. V., Shavyrin, A. S., Rykalin, V. I.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
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Summary:Triphenylantinony dimethacrylate Ph 3 Sb(O 2 CMe=CH 2 ) 2 was obtained in the reaction of triphenylantimony with methacrylic acid in the presence of hydrogen peroxide. The structure of the product was confirmed by elemental analysis, IR and 1 H NMR spectroscopy. According to X-ray diffraction analysis the substance is a trigonal bipyramidal complex of antimony with three phenyl groups in its basis and two methacrylate groups at the bipyramid vertices.
ISSN:1070-3632
1608-3350
DOI:10.1134/S107036321103008X