Gas-phase microreactors as a powerful tool for kinetic investigations

The purpose of this review was to show the versatility of gas-phase microreactors for the determination of kinetics of chemical systems. Precise kinetic models were demonstrated for two industrially relevant cases: (a) the continuous selective catalytic NO reduction by hydrocarbons in the excess oxy...

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Bibliographic Details
Published in:Russian journal of general chemistry 2012-12, Vol.82 (12), p.2034-2059
Main Authors: Hernández Carucci, J. R., Eränen, K., Salmi, T. O., Murzin, D. Yu
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Supplement: Rossiiskii Khimicheskii Zhurnal-Zhurnal Rossiiskogo Khimicheskogo Obshchestva im. D.I. Mendeleeva (Russian Chemistry Journal)
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Summary:The purpose of this review was to show the versatility of gas-phase microreactors for the determination of kinetics of chemical systems. Precise kinetic models were demonstrated for two industrially relevant cases: (a) the continuous selective catalytic NO reduction by hydrocarbons in the excess oxygen at 150–550°C and (b) the catalytic production of ethylene oxide, one of the most important intermediates in the world.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363212120250