Synthesis and structure of oxanorbornenes functionalized by nitro- and trichloromethyl groups

The reactions of furan and 2-methylfuran with 3,3,3-trichloro-1-nitro- and 1-bromo-3,3,3-trichloro-1-nitropropenes were studied to show that furan reacts by the diene condensation pathway, whereas the reactions with 2-methylfuran take two pathways: the diene synthesis and electrophilic substitution...

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Bibliographic Details
Published in:Russian journal of general chemistry 2014-02, Vol.84 (2), p.242-254
Main Authors: Anisimova, N. A., Slobodchikova, E. K., Berestovitskaya, V. M., Kuzhaeva, A. A., Ivanova, M. E., Rybalova, T. V.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
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Summary:The reactions of furan and 2-methylfuran with 3,3,3-trichloro-1-nitro- and 1-bromo-3,3,3-trichloro-1-nitropropenes were studied to show that furan reacts by the diene condensation pathway, whereas the reactions with 2-methylfuran take two pathways: the diene synthesis and electrophilic substitution by C 5 .
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363214020145