Synthesis and structure of novel dinitrosyl iron complexes [Fe2(μ-SCH2CH2NHR)2(NO)4]

Two novel dinitrosyl iron complexes with thiolate bridging ligands [Fe 2 (μ-SCH 2 CH 2 NHR) 2 (NO) 4 ] (R = Ac, Boc), derived from the cysteamine complex [Fe 2 (μ-SCH 2 CH 2 NH 3 ) 2 (NO) 4 ] 2+ are described. The complex with acylated cysteamine is characterized by X-ray diffraction analysis. The c...

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Bibliographic Details
Published in:Russian journal of general chemistry 2014-04, Vol.84 (4), p.719-721
Main Authors: Davidovich, P. B., Gurzhy, V. V., Belyaev, A. N.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
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Summary:Two novel dinitrosyl iron complexes with thiolate bridging ligands [Fe 2 (μ-SCH 2 CH 2 NHR) 2 (NO) 4 ] (R = Ac, Boc), derived from the cysteamine complex [Fe 2 (μ-SCH 2 CH 2 NH 3 ) 2 (NO) 4 ] 2+ are described. The complex with acylated cysteamine is characterized by X-ray diffraction analysis. The cysteamine complex is a convenient precursor for modification of the bridging ligand.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363214040203