Aryl(hetaryl)-containing gem-cyanonitroethenes: Synthesis, structure, and reactions with 2,3-dimethyl-1,3-butadiene

Methods of aryl(hetaryl)-substituted gem -cyanonitroethenes preparation are summarized, and the products structure elucidation by means of 1 H, 13 C NMR, IR, and UV spectroscopy methods is discussed. E -Configuration of the compounds obtained has been proved. Reaction of the studied gem -cyanonitroe...

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Bibliographic Details
Published in:Russian journal of general chemistry 2015-08, Vol.85 (8), p.1845-1854
Main Authors: Baichurin, R. I., Aboskalova, N. I., Trukhin, E. V., Berestovitskaya, V. M.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
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Summary:Methods of aryl(hetaryl)-substituted gem -cyanonitroethenes preparation are summarized, and the products structure elucidation by means of 1 H, 13 C NMR, IR, and UV spectroscopy methods is discussed. E -Configuration of the compounds obtained has been proved. Reaction of the studied gem -cyanonitroethenes with 2,3-dimethyl-1,3-butadiene affords the diene synthesis adducts–6-aryl(hetaryl)-3,4-dimethyl-1-nitro-1-cyano- 3-cyclohexenes.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363215080101