Structure formation of fullerene-containing propylene oxide oligomers in deuterium water

Structure formation of propylene oxide oligomers with terminal hydrophobic aliphatic fragment and of oligo(propylene oxides) additionally containing covalently bonded fullerene C 60 in deuterium water was studied by small-angle neutron scattering. Propylene oxide chains containing a long hydrophobic...

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Bibliographic Details
Published in:Russian journal of applied chemistry 2013-04, Vol.86 (4), p.568-574
Main Authors: Lebedev, V. T., Kul’velis, Yu. V., Orlova, D. N., Melenevskaya, E. Yu, Nasonova, K. V., Vinogradova, L. V.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Industrial Chemistry/Chemical Engineering
Macromolecular Compounds and Polymeric Materials
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Summary:Structure formation of propylene oxide oligomers with terminal hydrophobic aliphatic fragment and of oligo(propylene oxides) additionally containing covalently bonded fullerene C 60 in deuterium water was studied by small-angle neutron scattering. Propylene oxide chains containing a long hydrophobic fragment undergo organization into spherical micelles, whereas the fullerene(C 60 )-containing derivatives form rodlike structures (elongated “chains” of cross-linked micelles).
ISSN:1070-4272
1608-3296
DOI:10.1134/S1070427213040204