Ionic telomerization of 1-chloro-2,3-epoxypropane with allyl alcohol and properties of products obtained

Ionic telomerization of 1-chloro-2,3-epoxypropane with allyl alcohol in the presence of boron trifluoride etherate as a route to halogenated epoxy oligoethers was studied. Selective chlorination or bromination of the intermediate oligo(chlorohydrin), followed by dehydrochlorination (epoxidation) of...

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Bibliographic Details
Published in:Russian journal of applied chemistry 2013-09, Vol.86 (9), p.1364-1369
Main Authors: Kerimov, A. Kh, Orudzheva, A. T., Mamedova, Kh. A., Alieva, U. A.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Industrial Chemistry/Chemical Engineering
Organic Synthesis and Industrial Organic Chemistry
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Summary:Ionic telomerization of 1-chloro-2,3-epoxypropane with allyl alcohol in the presence of boron trifluoride etherate as a route to halogenated epoxy oligoethers was studied. Selective chlorination or bromination of the intermediate oligo(chlorohydrin), followed by dehydrochlorination (epoxidation) of the intermediate oligohalohydrins with NaOH, was performed. The synthesized products are effi cient as active diluents for a compound based on ED-20 resin.
ISSN:1070-4272
1608-3296
DOI:10.1134/S1070427213090084