Oligomeric hydroxy-aryloxy phosphazene based on cyclic chlorophosphazenes

Reaction of hexachlorocyclotriphosphazene and a mixture of cyclic chlorophosphazene [NPCl 2 ] n = 3–8 with an excess of diphenylolpropane under different conditions affords corresponding oligomeric hydroxy-aryloxy phosphazenes, which were characterized by gas chromatography-mass spectrometry, laser...

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Bibliographic Details
Published in:Russian journal of applied chemistry 2013, Vol.86 (12), p.1903-1912
Main Authors: Sirotin, I. S., Bilichenko, Yu. V., Brigadnov, K. A., Kireev, V. V., Suraeva, O. V., Borisov, R. S.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Industrial Chemistry/Chemical Engineering
Macromolecular Compounds and Polymeric Materials
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Summary:Reaction of hexachlorocyclotriphosphazene and a mixture of cyclic chlorophosphazene [NPCl 2 ] n = 3–8 with an excess of diphenylolpropane under different conditions affords corresponding oligomeric hydroxy-aryloxy phosphazenes, which were characterized by gas chromatography-mass spectrometry, laser mass spectrometry, 31 P and 1 H NMR spectroscopy. Side reactions was found with participation of decomposition products of diphenylolpropane.
ISSN:1070-4272
1608-3296
DOI:10.1134/S1070427213120161