Catalytic properties of RhSe2/Ga/H-ZSM-5 system in the reaction of glycerol dehydration in the gas phase

Catalytic properties of the RhSe 2 /Ga/H-ZSM-5 system formed upon thermal treatment of a mechanical mixture of rhodium selenochloride Rh 2 Se 9 Cl 6 and a gallium-containing zeolite Ga/H-ZSM-5 at 300–340°C in a flow of nitrogen were studied in the course of glycerol dehydration in the gas phase. It...

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Bibliographic Details
Published in:Russian journal of applied chemistry 2016-02, Vol.89 (2), p.233-237
Main Authors: Volkov, S. V., Khar’kova, L. B., Baranets, S. A., Yanko, O. G., Strizhak, P. E., Kosmambetova, G. R., Gritsenko, V. I.
Format: Article
Language:English
Subjects:
Catalysis
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Industrial Chemistry/Chemical Engineering
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Summary:Catalytic properties of the RhSe 2 /Ga/H-ZSM-5 system formed upon thermal treatment of a mechanical mixture of rhodium selenochloride Rh 2 Se 9 Cl 6 and a gallium-containing zeolite Ga/H-ZSM-5 at 300–340°C in a flow of nitrogen were studied in the course of glycerol dehydration in the gas phase. It was shown that the promotion of Ga/H-ZSM-5 with rhodium selenide RhSe 2 makes higher the yield of the target product acrolein.
ISSN:1070-4272
1608-3296
DOI:10.1134/S1070427216020117