Synthesis and spectral properties of sandwich meso-tetramethyltetrabenzoporphyrin-phthalocyanine complexes with lutetium, erbium, yttrium, and lanthanum

The reaction of phthalimide with zinc(II) propanoate gave meso -tetramethyltetrabenzoporphyrinatozinc(II) whose demetalation afforded the corresponding free base. The latter was used to synthesize complexes with lutetium, erbium, yttrium, and lanthanum. Heating of these complexes with excess phthalo...

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Published in:Russian journal of organic chemistry 2008-06, Vol.44 (6), p.921-926
Main Authors: Galanin, N. E., Yakubov, L. A., Shaposhnikov, G. P.
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Language:English
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Chemistry
Chemistry and Materials Science
Organic Chemistry
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description The reaction of phthalimide with zinc(II) propanoate gave meso -tetramethyltetrabenzoporphyrinatozinc(II) whose demetalation afforded the corresponding free base. The latter was used to synthesize complexes with lutetium, erbium, yttrium, and lanthanum. Heating of these complexes with excess phthalonitrile led to the formation of sandwich meso -tetramethyltetrabenzoporphyrin-phthalocyanine complexes. Spectral properties of the resulting compounds were studied.
doi_str_mv 10.1134/S1070428008060237
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subjects Chemistry
Chemistry and Materials Science
Organic Chemistry
title Synthesis and spectral properties of sandwich meso-tetramethyltetrabenzoporphyrin-phthalocyanine complexes with lutetium, erbium, yttrium, and lanthanum
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