Homophenalenyl cations, new representatives of homoaromatic systems

3b,4- exo ,4a,5-Tetramethyl-3b,4,4a,5-tetrahydro-4 H -cyclopropa[ a ]phenalen-5-yl cation and its endo -epimer were proved by NMR method to belong to a new kind of homoaromatic systems: homophenalenyl carbocations.

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Bibliographic Details
Published in:Russian journal of organic chemistry 2008-07, Vol.44 (7), p.1000-1005
Main Authors: Sal’nikov, G. E., Genaev, A. M., Mamatyuk, V. I., Shubin, V. G.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Organic Chemistry
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Summary:3b,4- exo ,4a,5-Tetramethyl-3b,4,4a,5-tetrahydro-4 H -cyclopropa[ a ]phenalen-5-yl cation and its endo -epimer were proved by NMR method to belong to a new kind of homoaromatic systems: homophenalenyl carbocations.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428008070099