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Alkylation of pyrocatechol in tert-butyl alcohol-sulfuric acid-benzene
Alkylation of pyrocatechol with tert -butyl alcohol in benzene in the presence of sulfuric acid gave 3,5-di- tert -butylbenzene-1,2-diol in a higher yield than in analogous reaction with tert -butyl alcohol. This result was rationalized by reduction of inhibitory effect of liberated water, formation...
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Published in: | Russian journal of organic chemistry 2011-09, Vol.47 (9), p.1310-1312 |
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Main Authors: | , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Alkylation of pyrocatechol with
tert
-butyl alcohol in benzene in the presence of sulfuric acid gave 3,5-di-
tert
-butylbenzene-1,2-diol in a higher yield than in analogous reaction with
tert
-butyl alcohol. This result was rationalized by reduction of inhibitory effect of liberated water, formation of heterogeneous system, and occurrence of the alkylation process in nonpolar organic phase. Intermediate products were identified and found to undergo intra- and intermolecular
tert
-butyl group transfer with formation of more stable 3,5-di-
tert
butylbenzene-1,2-diol. The formation of
p
-di-
tert
-butylbenzene indicated participation of benzene in crossalkylation processes. |
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ISSN: | 1070-4280 1608-3393 |
DOI: | 10.1134/S1070428011090089 |