Oxidation and reduction of 1,1′-[3-(methylsulfanylmethyl)tetrahydro-2H-thiopyran-3,5-diyl]diethanone

Oxidation of 1,1′-[3-(methylsulfanylmethyl)tetrahydro-2 H -thiopyran-3,5-diyl]diethanone with equivalent amounts of potassium iodate in glacial acetic acid and hydrogen peroxide in tetrahydrofuran and chloroform gave the corresponding mono- and disulfoxides and disulfone, respectively. Reactions of...

Full description

Saved in:
Bibliographic Details
Published in:Russian journal of organic chemistry 2012, Vol.48 (1), p.94-98
Main Authors: Baeva, L. A., Nikitina, T. S., Fatykhov, A. A., Galkin, E. G., Lyapina, N. K.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Organic Chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Oxidation of 1,1′-[3-(methylsulfanylmethyl)tetrahydro-2 H -thiopyran-3,5-diyl]diethanone with equivalent amounts of potassium iodate in glacial acetic acid and hydrogen peroxide in tetrahydrofuran and chloroform gave the corresponding mono- and disulfoxides and disulfone, respectively. Reactions of the title compound with sodium tetrahydridoborate and hydroxylamine hydrochloride afforded mono- and dihydroxy derivatives and monooxime, respectively.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428012010149