Synthesis and structure of Meisenheimer adducts in nucleophilic aromatic amination of 4,6-dinitrobenzofuroxan

Stable crystalline σ-complexes (Meisenheimer adducts) were isolated for the first time in the reactions of superelectrophilic 4,6-dinitrobenzofuroxan with dodecyl- and hexadecylamines, and their structure was determined by X-ray analysis.

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Bibliographic Details
Published in:Russian journal of organic chemistry 2013-04, Vol.49 (4), p.598-602
Main Authors: Galkina, I. V., Takhautdinova, G. L., Tudrii, E. V., Yusupova, L. M., Krivolapov, D. B., Litvinov, I. A., Cherkasov, R. A., Galkin, V. I.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Organic Chemistry
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Summary:Stable crystalline σ-complexes (Meisenheimer adducts) were isolated for the first time in the reactions of superelectrophilic 4,6-dinitrobenzofuroxan with dodecyl- and hexadecylamines, and their structure was determined by X-ray analysis.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428013040179