Variations in functional substitution of the macroheterocycle and structure of stable rhenium(V) porphyrins

Rhenium(V) porphyrin complexes with different natures of substituents and substitution patterns in the organic fragment (5,10,15,20-tetraphenylporphyrin, 2,3,7,8,12,13,17,18-octaethylporphyrin, 2,3,7,8,12,13,17,18-octaethyl-5-phenylporphyrin, and 2,3,7,8,12,13,17,18-octaethyl-5,15-diphenylporphyrin...

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Bibliographic Details
Published in:Russian journal of organic chemistry 2014-09, Vol.50 (9), p.1361-1368
Main Authors: Bichan, N. G., Tyulyaeva, E. Yu, Lomova, T. N., Semeikin, A. S.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Organic Chemistry
Review
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Summary:Rhenium(V) porphyrin complexes with different natures of substituents and substitution patterns in the organic fragment (5,10,15,20-tetraphenylporphyrin, 2,3,7,8,12,13,17,18-octaethylporphyrin, 2,3,7,8,12,13,17,18-octaethyl-5-phenylporphyrin, and 2,3,7,8,12,13,17,18-octaethyl-5,15-diphenylporphyrin dianions) and different axial ligands {phenoxide and chloride ions, 2′-(pyridin-4-yl)-5′-(pyridin-2-yl)-1′-(pyridin-3-ylmethyl)pyrrolidino[3′,4′: 1,9](C 60 - I h )[5,6]fullerene} have been synthesized, and their principal properties (spectral parameters and reactivity toward fullerene-containing base) have been studied.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428014090218