Polyfunctional imidazoles: XII.1 Synthesis of 1-[(4-chloro-1H-imidazol-5-yl)methyl]-substituted 1,2,3-triazoles and dihydropyrrolo[3,4-d]triazoles from 5-(azidomethyl)-4-chloro-1H-imidazoles

1-Aryl-5-(azidomethyl)-4-chloro-1 H -imidazoles reacted with terminal acetylenes in the presence of copper catalyst to give 1-[(1-aryl-4-chloro-1 H -imidazol-5-yl)methyl]-1 H -1,2,3-triazoles, and their reactions with N -arylmaleimides on heating in benzene afforded 5-aryl-1-[(1-aryl-4-chloro-1 H -i...

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Bibliographic Details
Published in:Russian journal of organic chemistry 2016-06, Vol.52 (6), p.873-878
Main Authors: Grozav, A. N., Chornous, V. A., Vovk, M. V.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Organic Chemistry
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Summary:1-Aryl-5-(azidomethyl)-4-chloro-1 H -imidazoles reacted with terminal acetylenes in the presence of copper catalyst to give 1-[(1-aryl-4-chloro-1 H -imidazol-5-yl)methyl]-1 H -1,2,3-triazoles, and their reactions with N -arylmaleimides on heating in benzene afforded 5-aryl-1-[(1-aryl-4-chloro-1 H -imidazol-5-yl)methyl]-3a,6a-dihydropyrrolo[3,4- d ][1,2,3]triazole-4,6(1 H ,5 H )-diones.
ISSN:1070-4280
1608-3393
DOI:10.1134/S107042801606018X