Radiative lifetime of the v′1(3P2) states of the HgAr, HgKr, and HgXe molecules and the probabilities A(v′, v″) of the v′1(3P2−v″0+(1S0) transitions

A semiempirical method of analysis of quasi-molecular terms in conjunction with experimental potentials of interaction of Hg(6( 3 P 1 )) atoms with Ar, Kr, and Xe atoms are used to obtain the Hg(6 3 P 2 )-Ar, Kr, Xe interaction potential, which are applied to calculating the radiative lifetimes of t...

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Bibliographic Details
Published in:Russian journal of physical chemistry. B 2011-12, Vol.5 (6), p.946-951
Main Authors: Alekseeva, O. S., Devdariani, A. Z., Zagrebin, A. L., Lednev, M. G.
Format: Article
Language:English
Subjects:
Chemical Physics of Atmospheric Phenomena
Chemistry
Chemistry and Materials Science
Physical Chemistry
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Summary:A semiempirical method of analysis of quasi-molecular terms in conjunction with experimental potentials of interaction of Hg(6( 3 P 1 )) atoms with Ar, Kr, and Xe atoms are used to obtain the Hg(6 3 P 2 )-Ar, Kr, Xe interaction potential, which are applied to calculating the radiative lifetimes of the v ′1( 3 P 2 ) states of the HgAr, HgKr, and HgXe molecules and the probabilities of the v ′1( 3 P 2 )− v ″0 + ( 1 S 0 ) transitions.
ISSN:1990-7931
1990-7923
DOI:10.1134/S1990793111060030