Physicomechanical and Elastic Properties of Polylactide–5,10,15,20-Tetrakis(4-n-hexyloxyphenyl)porphyrin Composite Materials

Porphyrin–polymer systems are promising materials for their use in biotechnology, biochemistry, and medicine. The creation of composite materials from porphyrins expands the possibilities of using both high molecular weight compounds and porphyrins. Polylactide–porphyrin film samples obtained by sol...

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Bibliographic Details
Published in:Polymer science. Series D, Glues and sealing materials Glues and sealing materials, 2024-09, Vol.17 (3), p.730-734
Main Authors: Tertyshnaya, Yu. V., Morokov, E. S., Zhdanova, K. A., Zakharov, M. S.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Polymer Sciences
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Summary:Porphyrin–polymer systems are promising materials for their use in biotechnology, biochemistry, and medicine. The creation of composite materials from porphyrins expands the possibilities of using both high molecular weight compounds and porphyrins. Polylactide–porphyrin film samples obtained by solution watering method are studied in this work. It was found that the density of the film compositions decreases with an increase in an amount of porphyrin in the polymer matrix. A Soret peak of porphyrin immobilized into the polylactide matrix splits (425 and 447 nm) and shifts bathochromically. The addition of 5,10,15,20-tetrakis(4- n -hexyloxyphenyl)porphyrin changes the elastic behavior and strength properties. Shear modulus, elastic modulus, and tensile strength decrease with an increase in an amount of porphyrin in the polylactide matrix. Relative elongation at break increases slightly, and the Poisson’s ratio is almost unchanged compared to those of starting polylactide.
ISSN:1995-4212
1995-4220
DOI:10.1134/S1995421224701259