Chamber Inhibitors of Corrosion of AMg6 Aluminum Alloy

• Published in: Protection of metals and physical chemistry of surfaces 2020-12, Vol.56 (7), p.1293-1298
• Main Authors: Goncharova, O. A., Kuznetsov, D. S., Andreev, N. N., Kuznetsov, Yu. I., Andreeva, N. P.
• Format: Article
• Language: English
• Subjects: Characterization and Evaluation of Materials; Chemistry and Materials Science; Corrosion and Coatings; Corrosion Inhibitors; Industrial Chemistry/Chemical Engineering; Inorganic Chemistry; Materials Science; Metallic Materials; Tribology
• ISSN: 2070-2051; 2070-206X
• DOI: 10.1134/S2070205120070060

Using a set of physicochemical (ellipsometry and contact angle measurements), electrochemical (potentiometric anode polarization and electrochemical impedance spectroscopy), and corrosion (periodic moisture condensation test) methods, the properties of adsorption films formed on the AMg6 aluminum alloy surface by the chamber method in vapors of some amines of heterocyclic compounds, carboxylic acids, and their salts are studied. It is established that the use of the studied compounds in the chamber processing of the alloy increases—though not effectively enough—its corrosion resistance in a humid atmosphere. The most promising inhibitors are carboxylic acids themselves; the optimum temperature for surface treatment with them is 140°C. One-hour treatment of steel with pairs of oleic, neodecanoic acid, and carboxylic acid A at this temperature gives rise to the formation of nanoscale adsorption films on the AMg6 alloy, which slightly hydrophilize the surface, but possess a protective aftereffect. Apparently, further improvement of chamber protection methods of the AMg6 alloy should consist in the selection of synergists for chamber corrosion inhibitors of the carboxylate type.