Radical displacement reactions: The vapor phase reaction of methyl radicals with allyl formate

Trideuteromethyl radicals have been reacted in the vapor phase with allyl formate and the principal reaction over the temperature range 100-250 °C has been shown to be the displacement reaction Hydrogen atoms generated by this decomposition also react readily to produce propylene by the reaction

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Bibliographic Details
Published in:Canadian journal of chemistry 1968-07, Vol.46 (14), p.2451-2454
Main Authors: Greig, G, Thynne, J. C. J
Format: Article
Language:English
Online Access:Get full text
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Summary:Trideuteromethyl radicals have been reacted in the vapor phase with allyl formate and the principal reaction over the temperature range 100-250 °C has been shown to be the displacement reaction Hydrogen atoms generated by this decomposition also react readily to produce propylene by the reaction
ISSN:0008-4042
1480-3291
DOI:10.1139/v68-397