Etude spectroscopique et voltammétrique de l'équilibre existant entre les acides chlorosulfurique et acétosulfurique dans l'acide acétique

A study of the Raman spectra of a solution of chlorosulfuric acid in acetic acid, under a continuous vacuum, reveals the existence of the equilibrium:[Formula: see text]The equilibrium constant of this reaction was determined from the study of the system:[Formula: see text]The equilibrium constant d...

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Bibliographic Details
Published in:Canadian journal of chemistry 1977-05, Vol.55 (10), p.1720-1727
Main Authors: Brasme, Bernard, Fischer, Jean Claude, Wartel, Michel
Format: Article
Language:English
Online Access:Get full text
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Summary:A study of the Raman spectra of a solution of chlorosulfuric acid in acetic acid, under a continuous vacuum, reveals the existence of the equilibrium:[Formula: see text]The equilibrium constant of this reaction was determined from the study of the system:[Formula: see text]The equilibrium constant derived from a least-squares analysis of the data was found to be10 0.8 ± 0.2  mol ℓ −1 . [Journal translation]
ISSN:0008-4042
1480-3291
DOI:10.1139/v77-243