Flash vacuum pyrolysis of anthracenic Diels-Alder adducts, a convenient source of methanethial and methanethial S-oxide

The flash vacuum pyrolysis of Diels-Alder adducts of anthracene constitutes a rapid and selective route to methanethial 1 and methanethial S-oxide 2 , as analyzed in the gas phase by photoelectron spectroscopy. Low temperature infrared and nuclear magnetic resonance ( 1 H, 13 C) spectra are also rep...

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Bibliographic Details
Published in:Canadian journal of chemistry 1987-02, Vol.65 (2), p.290-291
Main Authors: Vallee, Yannick, Ripoll, Jean-Louis, Lafon, Christophe, Pfister-Guillouzo, Geneviève
Format: Article
Language:English
Subjects:
Chemical reactivity
Chemistry
Exact sciences and technology
Organic chemistry
Reactivity and mechanisms
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Summary:The flash vacuum pyrolysis of Diels-Alder adducts of anthracene constitutes a rapid and selective route to methanethial 1 and methanethial S-oxide 2 , as analyzed in the gas phase by photoelectron spectroscopy. Low temperature infrared and nuclear magnetic resonance ( 1 H, 13 C) spectra are also reported for sulfine 2 .
ISSN:0008-4042
1480-3291
DOI:10.1139/v87-047