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Formation of As-Grown BiSrCaCuO Thin Films by Sputtering Three Targets Heavily Doped with Pb in Atmospheres of O 2 and N 2 O/O 2 Mixtures

As-grown BiSrCaCuO thin films have been formed on MgO(100) substrates at various temperatures by RF magnetron sputtering from three targets in atmospheres of neat O 2 and N 2 O/O 2 mixtures (1:1). The three targets had slightly different compositions heavily doped with Pb: Bi 3 Pb 3 Sr 2 Ca 2 Cu 3 O...

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Bibliographic Details
Published in:Japanese Journal of Applied Physics 1990-06, Vol.29 (6R), p.1066
Main Authors: Kuroda, Ken'ichi, Kojima, Kazuyoshi, Tanioku, Masami, Yokoyama, Kazuo, Kuroki, Hiroshi, Hamanaka, Koichi
Format: Article
Language:English
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Summary:As-grown BiSrCaCuO thin films have been formed on MgO(100) substrates at various temperatures by RF magnetron sputtering from three targets in atmospheres of neat O 2 and N 2 O/O 2 mixtures (1:1). The three targets had slightly different compositions heavily doped with Pb: Bi 3 Pb 3 Sr 2 Ca 2 Cu 3 O x , Bi 2 Pb 2 Sr 3 Ca 3 Cu 3 O x and Bi 2 Pb 2 Sr 2 Ca 2 Cu 4.5 O x . Both films formed in O 2 and N 2 O/O 2 mixtures at 660°C showed zero resistivity at 77–78 K. A film obtained at 540°C by N 2 O/O 2 mixtures showed superconductivity, while a film obtained at the same substrate temperature by neat O 2 did not. Gas mixtures of N 2 O and O 2 used instead of neat O 2 as a sputtering gas were effective in lowering the growth temperature by 20–40 degrees.
ISSN:0021-4922
1347-4065
DOI:10.1143/JJAP.29.1066