Mass Spectrometric Study of the Ln-LnI 3 (Ln = La, Ce) Systems

The Ln−LnI 3 (Ln = La, Ce) systems and their individual components LaI 3 and CeI 3 have been studied by the Knudsen effusion mass spectrometry (KEMS). Monomer LnI 2 , LnI 3 , dimmer Ln 2 I 6 molecules and positive and negative ions have been identified in the saturated vapor over these systems. The...

Full description

Saved in:
Bibliographic Details
Published in:ECS transactions 2013-08, Vol.58 (3), p.13-18
Main Authors: Ivanov, Dmitry A., Sergeev, Dmitry N., Dunaev, Anatoliy M., Kudin, Lev S., Butman, Mikhail F.
Format: Article
Language:English
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The Ln−LnI 3 (Ln = La, Ce) systems and their individual components LaI 3 and CeI 3 have been studied by the Knudsen effusion mass spectrometry (KEMS). Monomer LnI 2 , LnI 3 , dimmer Ln 2 I 6 molecules and positive and negative ions have been identified in the saturated vapor over these systems. The formation of LnI 2 in the Ln−LnI 3 systems during high temperature experiments has been determined.
ISSN:1938-5862
1938-6737
DOI:10.1149/05803.0013ecst