Graphene Quantum Dots from Partially Unzipped Multi-Walled Carbon Nanotubes: Promising Materials for Oxygen Electrodes

• Published in: Journal of the Electrochemical Society 2021-04, Vol.168 (4), p.44514
• Main Authors: Danilov, M. O., Fomanyuk, S. S., Dovbeshko, G. I., Gnatyuk, O. P., Rusetskyi, I. A., Kolbasov, G. Ya
• Format: Article
• Language: English
• ISSN: 0013-4651; 1945-7111
• DOI: 10.1149/1945-7111/abf4b3

Photoluminescent graphene quantum dots (GQDs) the one- or two-layer graphene nanoparticles 1.5–3 nm in size with a blue emission have been obtained from electrochemically synthesized partially unzipped multi-walled carbon nanotubes ultrasonically treated for one hour. Various physicochemical methods including photoluminescence spectroscopy, XRD, TEM, and Raman spectroscopy, have been used to characterize the electrochemically synthesized partially unzipped multi-walled carbon nanotubes and GQDs. Two-layer oxygen electrodes were fabricated, where GQDs served as an active layer. The investigations of electrocatalytic characteristics of the oxygen electrodes fabricated of the obtained materials were carried out in a fuel half-cell with an alkaline electrolyte. The fabricated oxygen electrodes were stable for six months at a discharge current density of 200 mA cm −2 . The obtained GQDs are promising materials as a new type of catalyst carriers for oxygen electrodes of fuel cells.