Electrochemical Pressure Impedance Spectroscopy for Polymer Electrolyte Membrane Fuel Cells: A Combined Modeling and Experimental Analysis

• Published in: Journal of the Electrochemical Society 2022-03, Vol.169 (3), p.34503
• Main Authors: Schiffer, Lutz, Shirsath, Anantrao Vijay, Raël, Stéphane, Bonnet, Caroline, Lapicque, François, Bessler, Wolfgang G.
• Format: Article
• Language: English
• Subjects: Chemical and Process Engineering; Engineering Sciences
• ISSN: 0013-4651; 1945-7111
• DOI: 10.1149/1945-7111/ac55cd

Electrochemical pressure impedance spectroscopy (EPIS) has recently been developed as a potential diagnosis tool for polymer electrolyte membrane fuel cells (PEMFC). It is based on analyzing the frequency response of the cell voltage with respect to an excitation of the gas-phase pressure. We present here a combined modeling and experimental study of EPIS. A pseudo-two-dimensional PEMFC model was parameterized to a 100 cm 2 laboratory cell installed in its test bench, and used to reproduce steady-state cell polarization and electrochemical impedance spectra (EIS). Pressure impedance spectra were obtained both in experiment and simulation by applying a harmonic pressure excitation at the cathode outlet. The model shows good agreement with experimental data for current densities ≤ 0.4 A cm −2 . Here it allows a further simulative analysis of observed EPIS features, including the magnitude and shape of spectra. Key findings include a strong influence of the humidifier gas volume on EPIS and a substantial increase in oxygen partial pressure oscillations towards the channel outlet at the resonance frequency. At current densities ≥ 0.8 A cm −2 the experimental EIS and EPIS data cannot be fully reproduced. This deviation might be associated with the formation and transport of liquid water, which is not included in the model.