Review—Earth-Abundant, Mn-Rich Cathodes for Vehicle Applications and Beyond: Overview of Critical Barriers

Broadening the portfolio of cathode active materials for Li-ion battery applications is now more important than ever. Recent focus on enabling diversity and security in supply chains, as well as concerns over sustainability of a massively growing energy storage market, have put emphasis on enabling...

Full description

Saved in:
Bibliographic Details
Published in:Journal of the Electrochemical Society 2023-03, Vol.170 (3), p.30509
Main Authors: Gutierrez, Arturo, Tewari, Deepti, Chen, Jiajun, Srinivasan, Venkat, Balasubramanian, Mahalingam, Croy, Jason R.
Format: Article
Language:English
Subjects:
ENERGY STORAGE
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c382t-f5db7a7bd76058767732028c9d4ff479c79bf2ded92f59c3569dd7dd41f9a4083
cites cdi_FETCH-LOGICAL-c382t-f5db7a7bd76058767732028c9d4ff479c79bf2ded92f59c3569dd7dd41f9a4083
container_end_page
container_issue 3
container_start_page 30509
container_title Journal of the Electrochemical Society
container_volume 170
creator Gutierrez, Arturo
Tewari, Deepti
Chen, Jiajun
Srinivasan, Venkat
Balasubramanian, Mahalingam
Croy, Jason R.
description Broadening the portfolio of cathode active materials for Li-ion battery applications is now more important than ever. Recent focus on enabling diversity and security in supply chains, as well as concerns over sustainability of a massively growing energy storage market, have put emphasis on enabling more Earth-abundant cathode materials as an attractive strategy. With respect to relatively near-term options, manganese-based cathodes are particularly interesting. Herein we discuss some of the challenges associated with advancing the development of manganese-based oxides and, in particular, those that take advantage of complex local structures and/or over-lithiated compositions. Discussion centers on the representative, lithium- and manganese-rich class of cathodes and considerations to future development are given that range from the atomic-scale to the electrode level.
doi_str_mv 10.1149/1945-7111/acbee4
format article
fullrecord <record><control><sourceid>iop_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1149_1945_7111_acbee4</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>jesacbee4</sourcerecordid><originalsourceid>FETCH-LOGICAL-c382t-f5db7a7bd76058767732028c9d4ff479c79bf2ded92f59c3569dd7dd41f9a4083</originalsourceid><addsrcrecordid>eNp1kMtKxDAUhoMoOF72LoMrF9ZJ2qRp3I2DN1CEQd2GNBeaoSYliSPufAif0Cexw4grXR3O4ft_OB8ARxidYUz4FHNCC4YxnkrVGkO2wOT3tA0mCOGqIDXFu2AvpeW44oawCegXZuXM29fH56WMuStm7avX0udTeO-LhVMdnMvcBW0StCHCZ9M51Rs4G4beKZld8AlKr-GFeQ9en8OHlYnrQhgsnEeXR6iHFzJGZ2I6ADtW9skc_sx98HR1-Ti_Ke4erm_ns7tCVU2ZC0t1yyRrNasRbVjNWFWislFcE2sJ44rx1pbaaF5aylVFa64105pgyyVBTbUPjje9IWUnknLZqE4F743KAvOalhSNENpAKoaUorFiiO5FxneBkVgrFWt_Yu1PbJSOkZNNxIVBLMNr9OMXYmmSwAyJSqAKUcTFoO2Inv6B_tv8DQ4Mhz4</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Review—Earth-Abundant, Mn-Rich Cathodes for Vehicle Applications and Beyond: Overview of Critical Barriers</title><source>Institute of Physics</source><creator>Gutierrez, Arturo ; Tewari, Deepti ; Chen, Jiajun ; Srinivasan, Venkat ; Balasubramanian, Mahalingam ; Croy, Jason R.</creator><creatorcontrib>Gutierrez, Arturo ; Tewari, Deepti ; Chen, Jiajun ; Srinivasan, Venkat ; Balasubramanian, Mahalingam ; Croy, Jason R. ; Argonne National Laboratory (ANL), Argonne, IL (United States) ; Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)</creatorcontrib><description>Broadening the portfolio of cathode active materials for Li-ion battery applications is now more important than ever. Recent focus on enabling diversity and security in supply chains, as well as concerns over sustainability of a massively growing energy storage market, have put emphasis on enabling more Earth-abundant cathode materials as an attractive strategy. With respect to relatively near-term options, manganese-based cathodes are particularly interesting. Herein we discuss some of the challenges associated with advancing the development of manganese-based oxides and, in particular, those that take advantage of complex local structures and/or over-lithiated compositions. Discussion centers on the representative, lithium- and manganese-rich class of cathodes and considerations to future development are given that range from the atomic-scale to the electrode level.</description><identifier>ISSN: 0013-4651</identifier><identifier>EISSN: 1945-7111</identifier><identifier>DOI: 10.1149/1945-7111/acbee4</identifier><identifier>CODEN: JESOAN</identifier><language>eng</language><publisher>United States: IOP Publishing</publisher><subject>ENERGY STORAGE</subject><ispartof>Journal of the Electrochemical Society, 2023-03, Vol.170 (3), p.30509</ispartof><rights>2023 The Electrochemical Society (“ECS”). Published on behalf of ECS by IOP Publishing Limited</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c382t-f5db7a7bd76058767732028c9d4ff479c79bf2ded92f59c3569dd7dd41f9a4083</citedby><cites>FETCH-LOGICAL-c382t-f5db7a7bd76058767732028c9d4ff479c79bf2ded92f59c3569dd7dd41f9a4083</cites><orcidid>0000-0002-3988-3125 ; 0000-0002-5839-3666 ; 0000-0002-2899-3089 ; 0000000228993089 ; 0000000258393666 ; 0000000239883125</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://www.osti.gov/servlets/purl/1965250$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Gutierrez, Arturo</creatorcontrib><creatorcontrib>Tewari, Deepti</creatorcontrib><creatorcontrib>Chen, Jiajun</creatorcontrib><creatorcontrib>Srinivasan, Venkat</creatorcontrib><creatorcontrib>Balasubramanian, Mahalingam</creatorcontrib><creatorcontrib>Croy, Jason R.</creatorcontrib><creatorcontrib>Argonne National Laboratory (ANL), Argonne, IL (United States)</creatorcontrib><creatorcontrib>Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)</creatorcontrib><title>Review—Earth-Abundant, Mn-Rich Cathodes for Vehicle Applications and Beyond: Overview of Critical Barriers</title><title>Journal of the Electrochemical Society</title><addtitle>JES</addtitle><addtitle>J. Electrochem. Soc</addtitle><description>Broadening the portfolio of cathode active materials for Li-ion battery applications is now more important than ever. Recent focus on enabling diversity and security in supply chains, as well as concerns over sustainability of a massively growing energy storage market, have put emphasis on enabling more Earth-abundant cathode materials as an attractive strategy. With respect to relatively near-term options, manganese-based cathodes are particularly interesting. Herein we discuss some of the challenges associated with advancing the development of manganese-based oxides and, in particular, those that take advantage of complex local structures and/or over-lithiated compositions. Discussion centers on the representative, lithium- and manganese-rich class of cathodes and considerations to future development are given that range from the atomic-scale to the electrode level.</description><subject>ENERGY STORAGE</subject><issn>0013-4651</issn><issn>1945-7111</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kMtKxDAUhoMoOF72LoMrF9ZJ2qRp3I2DN1CEQd2GNBeaoSYliSPufAif0Cexw4grXR3O4ft_OB8ARxidYUz4FHNCC4YxnkrVGkO2wOT3tA0mCOGqIDXFu2AvpeW44oawCegXZuXM29fH56WMuStm7avX0udTeO-LhVMdnMvcBW0StCHCZ9M51Rs4G4beKZld8AlKr-GFeQ9en8OHlYnrQhgsnEeXR6iHFzJGZ2I6ADtW9skc_sx98HR1-Ti_Ke4erm_ns7tCVU2ZC0t1yyRrNasRbVjNWFWislFcE2sJ44rx1pbaaF5aylVFa64105pgyyVBTbUPjje9IWUnknLZqE4F743KAvOalhSNENpAKoaUorFiiO5FxneBkVgrFWt_Yu1PbJSOkZNNxIVBLMNr9OMXYmmSwAyJSqAKUcTFoO2Inv6B_tv8DQ4Mhz4</recordid><startdate>20230301</startdate><enddate>20230301</enddate><creator>Gutierrez, Arturo</creator><creator>Tewari, Deepti</creator><creator>Chen, Jiajun</creator><creator>Srinivasan, Venkat</creator><creator>Balasubramanian, Mahalingam</creator><creator>Croy, Jason R.</creator><general>IOP Publishing</general><scope>AAYXX</scope><scope>CITATION</scope><scope>OIOZB</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000-0002-3988-3125</orcidid><orcidid>https://orcid.org/0000-0002-5839-3666</orcidid><orcidid>https://orcid.org/0000-0002-2899-3089</orcidid><orcidid>https://orcid.org/0000000228993089</orcidid><orcidid>https://orcid.org/0000000258393666</orcidid><orcidid>https://orcid.org/0000000239883125</orcidid></search><sort><creationdate>20230301</creationdate><title>Review—Earth-Abundant, Mn-Rich Cathodes for Vehicle Applications and Beyond: Overview of Critical Barriers</title><author>Gutierrez, Arturo ; Tewari, Deepti ; Chen, Jiajun ; Srinivasan, Venkat ; Balasubramanian, Mahalingam ; Croy, Jason R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c382t-f5db7a7bd76058767732028c9d4ff479c79bf2ded92f59c3569dd7dd41f9a4083</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>ENERGY STORAGE</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gutierrez, Arturo</creatorcontrib><creatorcontrib>Tewari, Deepti</creatorcontrib><creatorcontrib>Chen, Jiajun</creatorcontrib><creatorcontrib>Srinivasan, Venkat</creatorcontrib><creatorcontrib>Balasubramanian, Mahalingam</creatorcontrib><creatorcontrib>Croy, Jason R.</creatorcontrib><creatorcontrib>Argonne National Laboratory (ANL), Argonne, IL (United States)</creatorcontrib><creatorcontrib>Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV - Hybrid</collection><collection>OSTI.GOV</collection><jtitle>Journal of the Electrochemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gutierrez, Arturo</au><au>Tewari, Deepti</au><au>Chen, Jiajun</au><au>Srinivasan, Venkat</au><au>Balasubramanian, Mahalingam</au><au>Croy, Jason R.</au><aucorp>Argonne National Laboratory (ANL), Argonne, IL (United States)</aucorp><aucorp>Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Review—Earth-Abundant, Mn-Rich Cathodes for Vehicle Applications and Beyond: Overview of Critical Barriers</atitle><jtitle>Journal of the Electrochemical Society</jtitle><stitle>JES</stitle><addtitle>J. Electrochem. Soc</addtitle><date>2023-03-01</date><risdate>2023</risdate><volume>170</volume><issue>3</issue><spage>30509</spage><pages>30509-</pages><issn>0013-4651</issn><eissn>1945-7111</eissn><coden>JESOAN</coden><abstract>Broadening the portfolio of cathode active materials for Li-ion battery applications is now more important than ever. Recent focus on enabling diversity and security in supply chains, as well as concerns over sustainability of a massively growing energy storage market, have put emphasis on enabling more Earth-abundant cathode materials as an attractive strategy. With respect to relatively near-term options, manganese-based cathodes are particularly interesting. Herein we discuss some of the challenges associated with advancing the development of manganese-based oxides and, in particular, those that take advantage of complex local structures and/or over-lithiated compositions. Discussion centers on the representative, lithium- and manganese-rich class of cathodes and considerations to future development are given that range from the atomic-scale to the electrode level.</abstract><cop>United States</cop><pub>IOP Publishing</pub><doi>10.1149/1945-7111/acbee4</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0002-3988-3125</orcidid><orcidid>https://orcid.org/0000-0002-5839-3666</orcidid><orcidid>https://orcid.org/0000-0002-2899-3089</orcidid><orcidid>https://orcid.org/0000000228993089</orcidid><orcidid>https://orcid.org/0000000258393666</orcidid><orcidid>https://orcid.org/0000000239883125</orcidid><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0013-4651
ispartof Journal of the Electrochemical Society, 2023-03, Vol.170 (3), p.30509
issn 0013-4651
1945-7111
language eng
recordid cdi_crossref_primary_10_1149_1945_7111_acbee4
source Institute of Physics
subjects ENERGY STORAGE
title Review—Earth-Abundant, Mn-Rich Cathodes for Vehicle Applications and Beyond: Overview of Critical Barriers
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-29T04%3A49%3A37IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-iop_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Review%E2%80%94Earth-Abundant,%20Mn-Rich%20Cathodes%20for%20Vehicle%20Applications%20and%20Beyond:%20Overview%20of%20Critical%20Barriers&rft.jtitle=Journal%20of%20the%20Electrochemical%20Society&rft.au=Gutierrez,%20Arturo&rft.aucorp=Argonne%20National%20Laboratory%20(ANL),%20Argonne,%20IL%20(United%20States)&rft.date=2023-03-01&rft.volume=170&rft.issue=3&rft.spage=30509&rft.pages=30509-&rft.issn=0013-4651&rft.eissn=1945-7111&rft.coden=JESOAN&rft_id=info:doi/10.1149/1945-7111/acbee4&rft_dat=%3Ciop_cross%3Ejesacbee4%3C/iop_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c382t-f5db7a7bd76058767732028c9d4ff479c79bf2ded92f59c3569dd7dd41f9a4083%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true