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All-Wet Strip Approaches for Post-Etch Photoresist Layers After Low-K Patterning

Wet-only removal of post-etch (meth-)acrylate based photoresist on porous low-k dielectrics applied in either resist or metal hard mask based patterning is investigated. Characterization of photoresist degradation by etch is applied to support the selection of wet cleaning chemistries and/or cleanin...

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Bibliographic Details
Main Authors: Claes, Martine, Le, QuocToan, Kesters, Els, Lux, Marcel, Urionabarrenetxea, Ariana, Vereecke, Guy, Mertens, P., Carleer, R., Adriaensens, P.
Format: Conference Proceeding
Language:English
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Summary:Wet-only removal of post-etch (meth-)acrylate based photoresist on porous low-k dielectrics applied in either resist or metal hard mask based patterning is investigated. Characterization of photoresist degradation by etch is applied to support the selection of wet cleaning chemistries and/or cleaning processes. FTIR and 1H-NMR analysis results indicate a common degradation mechanism for both patterning schemes with formation of double carbon bonds in a cross-linked crust that is insoluble in organic solvents. Even though a common degradation method is observed, resist cleanability in metal hard mask applications is by far more difficult due to a higher degree of resist cross-linking. Cleaning approaches by dissolution in solvents in combination with physical forces, for both patterning schemes, are discussed in detail.
ISSN:1938-5862
1938-6737
DOI:10.1149/1.2779377