A Preliminary Investigation of Ductility-Enhancement Mechanism through In Situ Nanofibrillation in Thermoplastic Matrix Composites

• Published in: Journal of Polymers 2013-09, Vol.2013 (2013), p.1-9
• Main Authors: Patham, Bhaskar, Thejaswini, M. P. Poornendu
• Format: Article
• Language: English
• ISSN: 2356-7570; 2314-6877; 2314-6877
• DOI: 10.1155/2013/424015

A preliminary investigation of interrelationships between tensile stress-strain characteristics and morphology evolution during deformation is conducted on a commercially available thermoplastic composite with a low-surface-energy nanofibrillating poly(tetrafluoroethylene) (PTFE) additive. In this class of composites, the deformation-associated nanofibrillation of the low-surface-energy additive has been hypothesized to provide an additional dissipation mechanism, thereby enhancing the ductility of the composite. This class of composites offers potential for automotive light weighting in exterior and interior body and fascia applications; it is therefore of interest to investigate processing-structure-property interrelationships in these materials. This study specifically probes the interrelationships between the plastic deformation within the matrix and the fibrillation of the low-surface-energy additive; tensile tests are carried out at two different temperatures which are chosen so as to facilitate and suppress plastic deformation within the matrix polymer. Based on these preliminary investigations, it is noted that PTFE fibrillation acts synergistically with the ductile deformation of the matrix resin resulting in higher strains to failure of the composite; the results also suggest that the mechanism of fibrillation-assisted enhancement of strains to failure may not operate in the absence of matrix plasticity.