The Investigation of Dissociation of Trifluoroacetyl Fluoride in the Field of Pulsed CO 2 Laser

CF 3 COF dissociation channels in the pressure region from 0.2 to 4 Torr under the pulsed CO 2 laser radiation are investigated. The dissociation products COF 2 , C 2 F 6 , and CF 4 are identified according to the infrared spectra, and their relative output is measured over the whole range of the in...

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Bibliographic Details
Published in:Laser chemistry 1986-01, Vol.6 (6), p.373-380
Main Authors: Aslanidi, E. B., Zarubin, V. T., Turishchev, Yu. S.
Format: Article
Language:English
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Summary:CF 3 COF dissociation channels in the pressure region from 0.2 to 4 Torr under the pulsed CO 2 laser radiation are investigated. The dissociation products COF 2 , C 2 F 6 , and CF 4 are identified according to the infrared spectra, and their relative output is measured over the whole range of the initial substance pressures. A scheme of laserochemical reactions describing the trifluoroacetyl fluoride dissociation channels is presented. The correctness of the chosen scheme is confirmed on the basis of the elementary theory of active collisions. The measurements of CF 3 COF dissociation selectivity for 18 O and 13 C are given.
ISSN:0278-6273
1476-3516
DOI:10.1155/LC.6.373