CoPtW thin films prepared by magnetic electroplating

• Published in: Materials research innovations 2012-06, Vol.16 (3), p.179-185
• Main Authors: Yu, Y D, Guo, H F, Lou, J W, Ge, H L, Wei, G Y
• Format: Article
• Language: English
• Subjects: Agglomeration; Concentration (composition); CoPtW alloy film; Deposition; Electrodeposition; Electrodes; Magnetic electrodeposition; Magnetic fields; Magnetic properties; Magnetism; Thin films
• ISSN: 1432-8917; 1433-075X
• DOI: 10.1179/1433075X11Y.0000000056

CoPtW alloy films were prepared by magnetic electrodeposition method to replace conventional sputtering on copper substrate. The effects of different H 2 PtCl 6 concentrations and magnetic intensities on the composition, microstructure and magnetic properties of CoPtW alloy films were investigated. With the increasing H 2 PtCl 6 concentration, the amounts of Pt in CoPtW films increased dramatically, but the contents of both Co and W reduced gradually. Almost all of the deposited films were crystalline and contained CoPt(111), CoPt(002) and Co(002) peaks. The strongest perpendicular magnetic anisotropy could be observed when the H 2 PtCl 6 concentration was up to 0·02 mol L −1 . A higher H 2 PtCl 6 concentration would result in bigger and agglomerate nodular structures with lots of pores. The magnetic field parallel to the electrodes during the electrodeposition process could improve the deposition rate and increase the amounts of Co in CoPtW alloy films. Magnetic fields would induce cobalt growing along the (002) orientation. Films of smaller grain size and smooth surface could be formed under high magnetic intensity (0·8 T) as a result of magnetic force and magnetohydrodynamic effects. Moreover, a transition process from hard magnetism to soft magnetism could be observed when the magnetic intensity increased from 0 to 0·8 T.